Tim and Larissa Schuster are a successful couple in Clovis, California. Larissa owns a thriving biochemistry lab, while Tim works at a hospital and manages their home and two kids.

Two stories feature deadly wives willing to exchange love, for lust and greed. First, all-American girl, Morgan Wixon, meets small town boy, Kevin Mengel, and falls in love. The couple marries, has children, and owns a successful business together.

In the all-American town of Edgewood, Kentucky, Stephen and Adele Craven fit right in. He's a commercial airline pilot, and she's a stay-at-home mom with two adorable kids. Though they've been together for more than a decade, things aren't perfect.

Two stories feature deadly wives willing to do anything to make their husbands disappear. First, Lynn Stomps and her husband Gerry, live on a tree farm in Oregon. When the couple arranges to meet a buyer for their boat--everything goes wrong.

Two stories feature Southern wives desiring love--and money. First, country-girl Cristie Sehorne and her husband, Lee, have two children and live in Florida. Lee loves his work in commercial shipping, but his job requires long hours away at sea.

Two stories feature scheming wives incapable of telling the truth. First, Navy man Cory Voss and his wife Catherina "Cat" Voss are a young couple raising two children in Newport News, Virginia.

Two stories feature deadly wives that are the polar opposites of their partners. First, bubbly Rebecca Salcedo is a popular, young single mom with lots of friends. When she meets shy engineer Bruce Cleland, sparks fly--they share a whirlwind romance.

Sadie Proffitt and her husband David, 50, are a retired couple who move from Florida to Texas to be closer to Sadie's son. While Sadie is friendly with many residents at the sprawling apartment complex where they live.

his episode feature two stories of wives who weren't who they appeared to be. First, 30-year-old Ann Miller of Raleigh, NC seemed to have it all: a great job, a handsome husband and a beautiful baby. But Ann was leading a double life...and after her husband died suddenly of mysterious causes police were called in. Years later the mystery was finally unraveled. Then, in 2008, Chris Mason took her elderly husband Jim to the pool at her apartment complex for a little exercise. But when Jim ended up dead, investigators discovered the shocking truth about both Chris' past...and her plan to set herself free.

Teresa Stone is a traditional wife and mother of two in Independence, Missouri. Everyone in town knows that Randy, Teresa s husband, dotes on her--and the couple faithfully attends church together and own a successful local insurance agency. So when Randy is shot and killed in his office, the quiet community is stunned: who would want to kill such a likable family guy--a deacon, bus driver, and devoted member of New Hope Baptist church? While friends and family are shocked, Teresa remains surprisingly calm. As detectives begin to unravel the unusual case, they learn that sex, lies and greed are just a few of Teresa s unholy secrets, and each sinful revelation brings them one step closer to finding Randy s killer.

Elisa McNabney was living the high life in Sacramento, CA. Her husband Larry was a successful personal injury attorney, and since Larry's many TV commercials featured him in western gear, he was known as "The Marlboro Man." Elisa and Larry loved expensive things, and enjoyed traveling around the world to show their prized horses. Then one day Larry disappeared, but Elisa, with the help of a bright young college student named Sarah Dutra, still ran the law office in his absence. The two women were spending the practice's money as fast as they were making it. Then suddenly Elisa vanished too... and police had to untangle a web of lies and deception to solve the mystery of what happened to the Marlboro Man. And what they found shocked everyone.