Josh and Bill are forced back to their day jobs after their shine runs blue. Chico, under financial stress, makes a hard decision that could risk it all. Tickle struggles to keep Tim's old territory supplied. Mark and Jeff move their liquor.

It’s last call in shine country. Tim is thousands of cases of shine away from delivering the order of a lifetime. Mark & Digger receive the surprise of their lives in the middle of a shine sale. Josh is working on one last score and making amends.

Jeff, Mark and Lance head their separate ways; Tim gets to spend time with an old friend; Patti and David end their season with a boatload of shine.

Jeff, Mark and Lance's legendary partnership comes to a bittersweet end.

When a dead drop goes sideways, Mark Rogers deploys backwoods justice to straighten out a thief. Kelly's massive sorghum haul puts Mark and Digger's pot stills to the test. Mike & Daniel's clear apple pie has buyers calling from across county lines.

A year behind bars, Tickle transfers to Culpeper County, and Tim concocts a plan to get him out. Breaking the shiner code can come at a steep price for Mark Rogers. Mark & Digger's handmade vodka is on a hot streak until a cold snap puts profits at risk...

Mark and Digger's handmade vodka is on a hot streak until a cold snap threatens their run. For Mark Rogers, breaking the moonshiner code can come at a steep price. Tim Smith risks a big run of Tickle's double rye to put the woods back into his shine.

Mark and Digger build a hillbilly hack to save their handmade vodka. Pam may know more than she thinks about Popcorn's lost shine. Nothing but trouble for Josh running a still outside of the woods. Patti and David risk a seaplane bootleg on the bayou.

Tickle gets out of jail and Tim must keep him busy, but Tickle has ideas of his own. Mark and Digger make a discovery at Popcorn's boyhood home. On a midnight bootleg, Mark Rogers finds having the law on your side doesn't make you any less of an outlaw.

Tickle returns to Tim's legal distillery and discovers he's traded one prison for another. Mark and Digger unearth a trove of Popcorn's shine. Josh finds an untapped market at a biker rally, but learns the cost of entry is more than the ticket price.

Tickle’s back and funnier than ever after a year in jail; Josh, already in stitches, reveals an unexpected twist to his season, and Mark and Digger uncover how Popcorn’s shine-hoarding ways will pay off for Pam.

A subculture of distillers across America carries on the backwoods tradition of moonshining. Now, judged by legends Mark, Digger and Tim, America's top legal and outlaw shiners go head to head to see who wins the right to be called Master Distiller.

When Digger scores a tank of fresh milk, he and Mark attempt to solve the mystery of turning milk into moonshine; Tickle and Josh ramp up underground operations at the Law's rental house; hunting dogs invade Mike and Jerry's mountain still site.

Amanda returns to the mountains to help Mark and Huck crack the recipe for making shine from a rare breed of corn. Tim gets hands-on making old-school mezcal with volcanic rock and a horse-drawn stone wheel. Mike and Jerry attempt to make gin from quinoa.

Digger gets Daniel to attempt the first large-scale run of his innovative milk-based liquor recipe. Richard combines Digger's sea ageing with his own award-winning recipe to attempt his best liquor yet.

In the season finale, just as Mark and Digger undertake their large-scale bootleg to Nashville, the law makes an unwelcome return.

After losing their water source, Mark and Digger attempt to dig out a centuries-old spring; Josh tells Tickle and the Laws he can fell big timber for a 1,000 gallon still; Richard and Daniel form a Master Distiller dream team.

Evading the law, Mark and Digger attempt to make Scotch on a Popcorn Sutton-designed pot still. Amanda joins Mark and Huck in the hills only to find all their copper stolen. Richard and Daniel deploy game cameras to protect their own valuable stills.

Fed up with canned food and hiding in the woods, Josh gets into trouble with Kenny Law. Popcorn's son proves as unpredictable as his notorious dad. Tim and Howard rediscover a lost recipe for log still whiskey invented by a Kentucky teenager in 1836.

A police detective confronts Mark and Digger at the pump and doesn't mince words about his intent. Tickle and the Laws attempt to help as Josh's sanity erodes surviving in the woods. Tim and Howard construct a 19th century wood still from a giant log.

Mark and Digger score ten tons of sugar only to find a tracking device on their truck; Richard and Daniel devise a rum recipe to dominate the outlaw market; Mike and Jerry hit the jackpot with sweet-smelling mimosa liquor.

When weevils infest Mark and Digger's pricey grain, they must get rid of the bugs without killing their malt process. Tim and Howard fire up a log still with explosive consequences. Josh breaks out of his backwoods prison only to find himself up a creek.

In a rare lapse of judgment, Richard implodes Daniel's $3,000 copper still. As the fire marshal ramps up his investigation, Josh makes a tough decision to flee the country. Tim's solution to a centuries-old still build is going to sting a bit for Howard.

Seeking advice from Mark and Digger, Richard attempts to salvage the $3,000 copper still he imploded before Daniel returns. On the run from the law, Josh motors deep into the Brazilian highlands in search of a new recipe for caffeinated cachaça moonshine.

When Josh finds an outlaw operation in Brazil, he gets a hands-on lesson in how quickly he can turn sugar cane into high-proof liquor. In Maggie Valley, Mike and Jerry prepare to fight back when Richard and Craig start a backwoods operation on their turf.