Moonshine season in Appalachia has begun. Tim and Tickle are back, as we are introduced to some old school shiners -­ all looking to grab a piece of a $100 million dollar jackpot – tax free. But with a new lawman in town, everyone will be watching their backs.

A breakthrough is made on Josh and Bill's underground still; Mark and Jeff build a copper still.

Jim Tom helps Mark and Jeff repair a broken still; Mark hunts a wild hog.

A storm threatens Josh and Bill's underground still; Tickle goes rogue.

Tickle recruits a new partner and tries to find a new site after splitting from Tim; Mark, Jeff and Jim Tom start work on a second still; deputy sheriff Chuck infiltrates a moonshine operation.

Tickle builds a new still. Josh gets angry when he damages the nearly completed underground still site. Mark and Jeff make a risky move when they sell some of their product in town. Jim Tom teaches Jeff's son Lance how to measure the alcohol by volume concentration of moonshine.

Josh and Bill find mold in their underground still; Jeff's wife and son set up a second still.

Tickle gets busted by an angry landowner, while Tim devises an ingenious new hiding spot for his back-up stash of shine. Then, Josh & Bill get into a bone-breaking fight at their new still site. Also, Mark bootlegs moonshine by canoe in the dead of night.

Gunfire erupts in the bamboo patch just as Josh & Bill fire up their still for the first time this season. Meanwhile, Jeff, Mark & Jim Tom run a batch of President George Washington's rye whiskey. Then, Tickle hits the skids when his still is sabotaged.

Tim searches for 200 gallons of moonshine in a lake; Tickle finds his former helper; Jeff protects his still from an intruder; Mike uses horse manure for something other than gardening.

Tickle asks Tim for help; Jeff, Mark and Jim Tom battle a swarm of yellow jackets; and Josh rescues Cutie Pie.

In this season finale, one moonshiner will go down. Tickle devises a bold but risky plan to sell Tim's shine. Then, Josh & Bill's still site is compromised while Jeff, Mark & Jim Tom brazenly run three stills. Finally, Deputy Sheriff Chuck makes his move.

Josh and Bill are forced back to their day jobs after their shine runs blue. Chico, under financial stress, makes a hard decision that could risk it all. Tickle struggles to keep Tim's old territory supplied. Mark and Jeff move their liquor.

Tim is on the run after his operation was set on fire. Jim Tom prepares for his second coming as a moonshiner. Tickle & Tyler take their partnership to a new level. Josh & Bill sell last year's surplus shine. Jeff & Mark survey an indoor still site.

Tickle and Tyler need to fix a bad feed line and get back to work at the moonshine cave. Jim Tom and Roy build the still that will carry them to greatness. Josh and Bill are sidelined with a crushed still. Sheriff’s Deputy Chuck gains ground on Lance.

Josh and Bill rebuild bigger and better. Lance takes a risk on a new kind of whiskey, while Jeff and Mark prep their indoor still site. Tickle and crew battle the elements in Kentucky. Tim gives the North Carolina distillery a backwoods makeover.

Two former still hands of moonshine legend Popcorn Sutton emerge from the shadows. Tim learns that getting out of the illegal liquor business doesn’t get you out of the woods.

Tickle nails down a stash spot. Josh and Bill butt heads in the backwoods. Jim Tom and Roy are back in action. Mark and Digger's still goes from old school to state-of-the-art. And Mark and Jeff put the bells and whistles on their new shine spot.

Mark & Jeff feel the heat as the law closes in. Tim's plan to give a backwoods makeover to Troy's distillery will cost him big. Tickle flirts with disaster as he tries to sell his Kentucky made white lightning.

Tickle has his hands full keeping track of his liquor and Chico and Tyler are becoming suspicious. Bill and Josh build an underground bunker to hide their shine. Tennessee shiners, Mark and Digger, test an invention that could revolutionize moonshining.

Josh and Bill have a close call with authorities; a new lawman visits two shiners in Tennessee; Tickle learns a lesson the hard way.

Josh and Bill have a triple batch run; Tickle makes a sacrifice to save his partnership; Tim is ready to see if the Asheville distillery can produce his moonshine.

The final weeks of shine season are here. Josh & Bill's liquor gets stuck six feet under. Chico & Tyler brew a sweet & sticky moonshine game-changer. Tickle gets trumped by his old buddy. And Mark & Jeff's first sale on the water ends in disaster.

Josh and Bill secretly sell their shine; Tim returns to Virginia to fill an order; Mark tries to make a delivery by boat; Tickle's deal nearly breaks down.

Tickle takes risks to stay true to his old partner; Josh and Bill make a last run in the woods; Mark and Digger's season is in danger when their deal backfires.