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Gotham City is literally held in the grip of terror by The Scarecrow's arsenal of Fear Transmitters. Scouring Gotham in search of Scarecrow, Batman is himself paralyzed with fright when he finds himself in the middle of Crime Alley, where years earlier the parents of Batman's alter ego Bruce Wayne had been murdered in cold blood. Taking advantage of the situation, Scarecrow intends to keep Batman trapped in Crime Alley forever by using a captured Robin and Wonder Woman as bait—forcing the Caped Crusader to purge himself of his lifelong fears once and for all!

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In a parallel universe, the Super Friends are supervillains, the Super Enemies. Mount Vesuvius is a focal point that links the two universes — in one universe, Superman tries to stop the eruption, while his evil counterpart is causing the same disaster in his own reality. Vesuvius explodes, causing the two Supermen to exchange universes. While Superman has to fight his evil comrades and find a way back to his own world, his evil counterpart battles the real heroes and begins his plan to conquer Earth.

Big Foot: Apache Chief and few of his fellow braves are captured by alien creatures resembling the legendary Bigfoot. Batman and Robin try to help, but are also captured. After they escape and defeat the creatures, the Super Friends learn that they were merely trying to seek information to repair their spacecraft. The Ice Demon: While on a skiing vacation, the Wonder Twins literally bump into a pair of reckless teenagers and wind up in an ice cave inhabited by an Ice Demon. Only Superman can save them. Luckily, Clark Kent and Lois Lane are nearby. The Make-Up Monster: A disgruntled make-up man on the set of a movie discovers a formula that allows him to make himself up into any powerful monster he chooses. With the formula, he wreaks havoc and wrecks the movie studio and only the Super Friends dare to challenge him.

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Lex Luthor forms a criminal gang called the Legion of Doom and uses a dream-machine to make the Super Friends commit crimes.

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What starts off as a camping trip for the Wonder Twins turns into a nightmarish adventure in Middle Earth when the Super Friends must battle a black magic sorcerer named Mal Havok who has taken over the troll kingdom. Mal Havoc uses his magic to turn the Super Friends into trolls. With their powers reduced, Batman and Wonder Woman accompany the troll king on a mission to free Middle Earth of the evil sorcerer.

Journey into Blackness: While monitoring the galaxy from his impenetrable Fortress of Solitude, Superman notices a black hole that is going to suck up the Earth. Superman attempts to stop it, but gets himself pulled into the black hole. The Cycle Gang: The Highway Angels, a motorcycle gang, start tormenting a senior citizen and his grandson. When the Wonder Twins try to help they have a hard time dealing with the cycle gang and the danger at hand. Wonder Woman sees the twins and gives them assistance. Dive to Disaster: Several miles off the coast of Hawaii, a routine Navy mission becomes a nightmare when a submarine's controls short circuits and the nuclear reactor starts to overload. Black Vulcan and Aquaman try to help, but are attacked by nuclear mutated sea creatures.

Return of the Phantoms: The three Phantom Zone villains: Logar, Hol, and Romlok are freed by an alien who doesn't realize they are criminals. In this episode they force the alien to travel back in time with them in an attempt to alter Superboy's life—hoping that he will never grow up to become Superman. Meanwhile, in the future, Superman and Green Lantern learn of the plot from the alien and travel back in time to save Superman's own past and capture the Phantom Zone villains. Bully for You: Teen angst and bullying are spotlighted at the start of this episode. In the meantime, after a daring mission on a skyscraper, Batman loses his utility belt. The boy who was being bullied finds the belt and seeks revenge. Unfortunately, the boy doesn't know what all power that the belt contains and he accidentally switches on a high frequency signal that leads to Earth shaking effects and building destruction.

Darkseid's Golden Trap: Part I: At an intergalactic auction, Darkseid and his crew set their eyes on gold kryptonite. It's the only chunk of gold kryptonite, which can permanently strip away all of the powers that Superman enjoys on Earth. known to be in existence. Black Vulcan, Wonder Woman, and Firestorm infiltrate the auction under disguise as ice creatures. They plan on bidding high and taking the gold kryptonite before it can fall into enemy hands, but Darkseid soon realizes their plan. Darkseid's Golden Trap: Part II: Darkseid catches onto the trick and plots an elaborate scheme to expose Superman to the gold kryptonite that he won. El Dorado, Batman, and Superman travel to the Moon of Games to confront Kalibak about which star has Darkseid imprisoned Black Vulcan, Wonder Woman, and Firestorm. El Dorado hatches a plan with the help of Batman. Darkseid shows up unexpectedly, as El Dorado had feared, and Darkseid throws the gold kryptonite at Superman... but did it work?