In the first show in the new series of The Wine Show, Matthew Goode welcomes new face James Purefoy to their beautiful new villa in France. Together they are tasked with putting together a case of wine to match a six-course lunch made by Michelin starred French chef Stéphane Reynaud. Judging which wine goes in the case, is the world’s most influential wine critic Jancis Robinson. This week it’s pre-lunch snacks they have to match and they head to Provence for rosé wine in the charming town of Cotignac. Joe Fattorini is off on his travels too. He’s with comedian Gina Yashere in Santa Barbara learning how a cup of coffee can predict what kind of wine you might like. As Joe tries to convince Gina he will find a wine for her sensitive palate, she reveals a surprise of her own for Joe. Back in the UK, Matthew Rhys is in glamorous and historic London St James’s on his quest to find gadgets old and new.

In the second show in the new series, Matthew Goode and James Purefoy are in search of a wine to match the starter in their epic six-course lunch. They get an early morning call in the Ardeche before heading up the river in a kayak and caving their way to a very unusual wine cellar. Back at the villa, Jancis Robinson chooses her favourite wine of the two they bring back. Meanwhile, Joe Fattorini has been in Argentina to find out about a very successful immigrant and heads to Japan with top London brewer Jaega Wise to find out about sake. Back in London, Matthew Rhys is at Berry Brothers & Rudd in London's St James's looking at historic and modern gadgets.

In the third show in the new series, James Purefoy and Matthew Goode think they're in for a fabulous lunch at the glamorous Palme D'Or restaurant in Cannes. Little do they know the chef has decided they need to work for their lunch. But they each find a wine to take back for Jancis Robinson to assess as a match to the fish course of Stephane Reynaud's epic six-course lunch. Meanwhile Joe Fattorini has been to the former Soviet republic of Georgia, to find out if it really can lay claim to being the cradle of wine. And Joe joins wine expert Amelia Singer in California to find out how one sheriff is helping a local wine maker find people to work in her vineyard at a time of historic labour shortages. Back in London, Matthew Rhys is at Berry Brothers & Rudd in London's St James's looking at historic and modern gadgets.

Joe chases down wine in the Médoc. Matthew and James head to Burgundy to find a match for Coq au vin. Matthew Rhys pours and spills wine. Amelia and Joe learn more about the emerging wine regions of British Colombia.

In the fifth show in the new series, James Purefoy and Matthew Goode are in the Camargue on the hunt for wines to match the cheese course in the epic French lunch. In an effort to understand the Camargue way of life, they become cowboys for the day, rounding up bulls before they are allowed to sit down and taste some wines. With their wines chosen they head back to the villa for the judgement of Jancis Robinson, the world's most influential wine critic. Joe Fattorini is in Bosnia to find out how one vineyard is trying to heal some very open wounds of war. And he joins Amelia Singer in St Tropez for an inspiring beach lunch with legendary winemaker Sacha Lichine before getting aboard the cruise ship Celebrity Reflection to host a VIP wine dinner. And back in London, Matthew Rhys is at Berry Brothers & Rudd in London's St James's looking at historic and modern gadgets.

James Purefoy and Matthew Goode are baking in Lyon to find a wine for the dessert. Joe Fattorini is in San Sebastian, Spain with chef Jose Pizarro. Jaega Wise is tasked with trying to convince Joe that he should really be drinking beer in a very festive Munich Matthew Rhys with his gadgets.

The last show of the current series of The Wine Show is a Food & Wine special. Hosts James Purefoy and Matthew Goode introduce us to six wines chosen by some of the world's greatest sommeliers. In their restaurants around the world, the chefs create some inspiring wine and food pairings. We visit the legendary Pied de Terre on London's Charlotte Street, new sensation Single Thread Farm in California, the unique Bubbledogs Kitchen Table in London, Bel Canto in Lisbon, the stunning Lime Wood in Hampshire and the ground-breaking Dairy in Clapham, South London. We also revisit some of the highlights of Matt and James's journey around France.